|Table of Contents|

Properties and modification mechanism of high toughness concrete modified with compound latex powder(PDF)

长安大学学报(自然科学版)[ISSN:1006-6977/CN:61-1281/TN]

Issue:
2026年01期
Page:
78-89
Research Field:
道路工程
Publishing date:

Info

Title:
Properties and modification mechanism of high toughness concrete modified with compound latex powder
Author(s):
LI Xiang-nan1 FENG Zhen-gang1* JI Hong-ru2 YAO Dong-dong3 CUI Qi1 LI Xin-jun1
(1. School of Highway, Chang'an University, Xi'an 710064, Shaanxi, China; 2. Guangzhou Municipal Transportation Bureau, Guangzhou 510630, Guangdong, China; 3. Jilin Provincial Transport Science Research Institute, Changchun 130012, Jilin, China)
Keywords:
road engineering high toughness concrete experimental research latex powder toughness frost resistance modification mechanism
PACS:
U414
DOI:
10.19721/j.cnki.1671-8879.2026.01.006
Abstract:
To synergistically enhance the toughness of high toughness concrete(HTC)and its durability during service in seasonal freezing region, the HTC specimens with different compounding ratios were modified by ethylene-vinyl acetate(EVA)latex powder compounded with styrene butadiene(SB)latex powder and styrene acrylate(SA)latex powder, respectively. The mechanical properties and toughness of HTC were evaluated by strength and flexural compression ratio. The durability of HTC was evaluated by freeze-thaw test and salt ion freeze-thaw cycling test. The microstructure and modification mechanism of HTC modified by compound latex powder were investigated by scanning electron microscopy and mercury intrusion porosimetry test. The results show that, compared to EVA-modified HTC(HTC1), both EVA/SB-modified HTC(HTC2)and EVA/SA-modified HTC(HTC3)show significant improvement in flexural strength and toughness. EVA/SB and EVA/SA can both enhance the frost and salt-freeze resistance of HTC, but EVA/SA improvement is more significant. Compared to HTC1, the interface transition zones in HTC2 and HTC3 are more tightly bonded with fewer internal voids, resulting in a denser structure. The porosity of HTC2 and HTC3 was lower, and the pore structure distribution was more reasonable. EVA/SA show a more significant improvement in the pore structure of HTC compared to EVA/SB, which can be attributed to the ability of compounded latex powder to polymerize into a membrane within HTC, forming a network structure with the hydration products of cement. At the same time, the latex powders and their membrane structures fill the pores, improving the interface transition zone and pore structure of HTC. The findings provide theoretical guidance and feasible pathways for the durability design and performance optimization of high toughness concrete in seasonal freeze-thaw regions, positively contributing to the service safety and lifespan of engineering structures in cold regions.10 tabs, 8 figs, 32 refs.

References:

[1] 袁 晟,颜东煌,袁 明,等.养护方式和早龄期对钢纤维-UHPC基体界面黏结性能的影响[J].长安大学学报(自然科学版),2022,42(6):133-142.
YUAN Sheng, YAN Dong-huang, YUAN Ming, et al. Effect of curing method and early age on interface bonding properties of steel fiber-UHPC matrix[J]. Journal of Chang'an University(Natural Science Edition), 2022, 42(6): 133-142.
[2]樊健生,丁 然.超高性能混凝土在房屋建筑结构中的研究与应用进展[J].硅酸盐学报,2023,51(5):1246-1258.
FAN Jian-sheng, DING Ran. Research and application progress of ultra-high performance concrete in building structure[J]. Journal of the Chinese Ceramic Society, 2023, 51(5): 1246-1258.
[3]王伯昕,高银龙,王 清,等.冻融循环对季冻土区粉质黏土-混凝土界面剪切性能的影响[J].吉林大学学报(地球科学版),2024,54(5):1592-1603.
WANG Bo-xin, GAO Yin-long, WANG Qing, et al. Effect of freeze-thaw cycle on shear properties of silty clay-concrete interface in seasonal frozen soil[J]. Journal of Jilin University(Earth Science Edition), 2024, 54(5): 1592-1603.
[4]崔圣爱,张书豪,曾慧姣,等.纳米增强超高韧性混凝土纤维分布及弯曲性能[J].东南大学学报(自然科学版),2025,55(1):131-139.
CUI Sheng-ai, ZHANG Shu-hao, ZENG Hui-jiao, et al. Fiber distribution and bending performance of nano reinforced ultra-high toughness concrete[J]. Journal of Southeast University(Natural Science Edition), 2025, 55(1): 131-139.
[5]吴建华,蒲心诚,刘 芳.大掺量粉煤灰高性能混凝土配制技术[J].重庆大学学报(自然科学版),2005,28(5):54-58.
WU Jian-hua, PU Xin-cheng, LIU Fang. Preparation technology of high performance concrete with large amount of fly ash[J]. Journal of Chongqing University(Natural Science Edition), 2005, 28(5): 54-58.
[6]刘 洋,欧忠文,胡志德,等.高韧性混凝土复合材料研究与应用进展[J].合成纤维,2019,48(9):43-46.
LIU Yang, OU Zhong-wen, HU Zhi-de, et al. Progress in research and application of high toughness concrete composites[J]. Synthetic Fiber in China, 2019, 48(9): 43-46.
[7]郭寅川,申爱琴,王胜难,等.季冻区路面混凝土界面区劣化行为及与强度相关性[J].中国公路学报,2019,32(8):49-57.
GUO Yan-chuan, SHEN Ai-qin, WANG Sheng-nan, et al. Deterioration behavior of pavement concrete interface in seasonal freezing zone and its correlation with strength[J]. China Journal of Highway and Transport, 2019, 32(8): 49-57.
[8]申爱琴,陈荣伟,郭寅川,等.季冻区纳米SiO2改性SAP路面混凝土的耐磨性[J].材料导报,2024,38(7):60-65.
SHEN Ai-qin, CHEN Rong-wei, GUO Yan-chuan, et al. Wear resistance of SAP pavement concrete modified with nano SiO2 in seasonal freezing zone[J]. Materials Reports, 2024, 38(7): 60-65.
[9]熊剑平,申爱琴,魏越强,等.聚合物水泥混凝土的路用性能[J].长安大学学报(自然科学版),2007,27(6):24-28.
XIONG Jian-ping, SHEN Ai-qin, WEI Yue-qiang, et al. Road performance of polymer cement concrete[J]. Journal of Chang'an University(Natural Science Edition), 2007, 27(6): 24-28.
[10]张 娜,董文乔,王婉申,等.聚合物粉末对水泥砂浆抗冻性能的影响研究[J].混凝土世界,2023(7): 32-39.
ZHANG Na, DONG Wen-qiao, WANG Wan-shen, et al. Study on the influence of polymer powder on the frost resistance of cement mortar[J]. China Concrete, 2023(7): 32-39.
[11]王培铭,赵国荣,张国防.可再分散乳胶粉在水泥砂浆中的作用机理[J].硅酸盐学报,2018,46(2):256-262.
WANG Pei-ming, ZHAO Guo-rong, ZHANG Guo-fang. Mechanism of redispersible emulsion powder in cement mortar[J]. Journal of the Chinese Ceramic Society, 2018, 46(2): 256-262.
[12]吴彰钰,佘 伟,缪昌文.仿生高韧水泥基复合材料制备技术及增韧机理[J].东南大学学报(自然科学版),2024,54(1):1-8.
WU Zhang-yu, SHE Wei, MIU Chang-wen. Preparation technology and toughening mechanism of bionic high toughness cement-based composites[J]. Journal of Southeast University(Natural Science Edition), 2024, 54(1): 1-8.
[13]王宇峰,陈钱宝,梅晓君,等.掺杂EVA胶粉的硫铝酸盐-硅酸盐复合防腐砂浆制备及性能研究[J].胶体与聚合物,2022,40(1):3-7.
WANG Yu-feng, CHEN Qian-bao, MEI Xiao-jun, et al. Preparation and properties of sulphoaluminate-silicate composite anticorrosive mortar doped with EVA rubber powder[J]. Chinese Journal of Colloid & Polymer, 2022, 40(1): 3-7.
[14]王军伟,李 昊,李文秀,等.聚灰比对聚合物砂浆性能影响研究[J].高速铁路新材料,2023,2(4):30-33.
WANG Jun-wei, LI Hao, LI Wen-xiu, et al. Study on the effect of cementing ratio on the properties of polymer mortar[J]. Advanced Materials of High Speed Railway, 2023, 2(4): 30-33.
[15]魏玉荣,魏 茂.EVA对水泥水化影响的研究[J].中国水泥,2019(4):87-91.
WEI Yu-rong, WEI Mao. Study on the effect of EVA on cement hydration[J]. China Cement, 2019(4): 87-91.
[16]SAKAI E, NAKAJIMA K, KUBOKAWA T. Polymer-modified cement using belite-rich cement and carbonation reaction[J]. Construction & Building Materials, 2016, 110(5): 333-336.
[17]KHAN K A, AHMAD I, ALAM M. Effect of ethylene vinyl acetate(EVA)on the setting time of cement at different temperatures as well as on the mechanical strength of concrete[J]. Arabian Journal for Science and Engineering, 2018, 44(4): 4075-4084.
[18]肖 畅,王 开,张小强.EVA和钢纤维改性混凝土力学特性研究[J].矿业研究与开发,2021,41(8):65-69.
XIAO Chang, WANG Kai, ZHANG Xiao-qiang. Study on mechanical properties of EVA and steel fiber modified concrete[J]. Mining Research and Development, 2021, 41(8): 65-69.
[19]师海霞,孔祥明,范德科,等.苯丙乳液改性混凝土微观结构与性能研究[J].混凝土世界,2010(9):60-65.
SHI Hai-xia, KONG Xiang-ming, FAN De-ke, et al. Study on microstructure and properties of styrene acrylic emulsion modified concrete[J]. China Concrete, 2010(9): 60-65.
[20]CHENG J, SHI X, XU L, et al. Investigation of the effects of styrene acrylate emulsion and vinyl acetate ethylene copolymer emulsion on the performance and microstructure of mortar[J]. Journal of Building Engineering, 2023, 75: 106965.
[21]FENG Z G, GONG X R, LI X N, et al. Mechanical properties and durability of high toughness concrete(HTC)modified by EVA and SB latex powder[J]. Journal of Testing and Evaluation, 2024, 52(1): 446-459.
[22]WANG R, WANG P M, LI X G. Physical and mechanical properties of styrene-butadiene rubber emulsion modified cement mortars[J]. Cement and Concrete Research, 2005, 35(5): 900-906.
[23]XIONG Z, TANG Z, HE S, et al. Analysis of mechanical properties of rubberized mortar and influence of styrene-butadiene latex on interfacial behaviour of rubber-cement matrix[J]. Construction and Building Materials, 2021, 300(9): 124027.
[24]王 茹,王培铭.丁苯乳液和乳胶粉对水泥水化产物形成的影响[J].硅酸盐学报,2008(7):912-919,926.
WANG Ru, WANG Pei-ming. Effect of butadiene emulsion and emulsion powder on the formation of hydration products of cement[J]. Journal of the Chinese Ceramic Society, 2008(7): 912-919, 926.
[25]王 娣,何 浪,余 越,等.可聚合乳化剂复配体系对聚合前后苯丙乳液性能的影响规律研究[J].涂料工业,2019,46(5):7-11.
WANG Ti, HE Lang, YU Yue, et al. Study on the influence of polymerizable emulsifier compound system on the properties of styrene acrylic emulsion before and after polymerization[J]. Paint & Coatings Industry, 2019, 46(5): 7-11.
[26]唐佳军,李九阳,王 坦.改性混凝土的拉压比与折压比分析[J].工程建设,2020,52(12):12-16.
TANG Jia-jun, LI Jiu-yang, WNAG Tan. Analysis of tensile compression ratio and folding compression ratio of modified concrete[J]. Engineering Construction, 2020, 52(12): 12-16.
[27]何倩倩,姚金水,张希岩.可再分散乳胶粉的研究进展及应用前景[J].涂料工业,2007,37(5):52-54,58.
HE Qian-qian, YAO Jin-shui, ZHANG Xi-yan. Research progress and application prospect of redispersible emulsion powder[J]. Paint & Coatings Industry, 2007, 37(5): 52-54, 58.
[28]王培铭,刘恩贵.苯丙共聚乳胶粉水泥砂浆的性能研究[J].建筑材料学报,2009,12(3):253-258,265.
WANG Pei-ming, LIU En-gui. Study on the properties of styrene propylene copolymer emulsion powder cement mortar[J]. Journal of Building Materials, 2009, 12(3): 253-258, 265.
[29]刘 方,王宝民,袁晓洒,等.丁苯胶乳改性水泥混凝土的力学性能及耐久性实验分析[J].功能材料,2019,50(6):167-173.
LIU Fang, WANG Bao-min, YUAN Xiao-sa, et al. Experimental analysis of mechanical properties and durability of styrene butadiene latex modified cement concrete[J]. Journal of Functional Materials, 2019, 50(6): 167-173.
[30]秦立军,白二雷,王志航,等.聚合物乳胶粉改性碳纤维增强混凝土的配合比设计[J].空军工程大学学报,2023,24(5):102-110.
QIN Li-jun, BAI Er-lei, WANG Zhi-hang, et al. Mix ratio design of polymer emulsion powder modified carbon fiber reinforced concrete[J]. Journal of Air Fouce Engineering University(Natrnal Science Edition), 2023, 24(5): 102-110.
[31]BHOGAYATA A C, ARORA N K. Workability, strength, and durability of concrete containing recycled plastic fibers and styrene-butadiene rubber latex[J]. Construction and Building Materials, 2018, 180: 382-395.
[32]ROOPA V, DHARMA R B, MOHAMMED M S H S, et al. Durability and microstructure studies of styrene acrylate co-polymer modified ready-mix concrete[J]. Journal of Structural Engineering, 2022, 49(5): 358-372.

Memo

Memo:
-
Last Update: 2026-02-20