|Table of Contents|

Research progress in application of strontium aluminate long afterglow luminescent materials in road markings(PDF)

长安大学学报(自然科学版)[ISSN:1006-6977/CN:61-1281/TN]

Issue:
2022年3期
Page:
1-13
Research Field:
道路工程(道路交通功能材料专刊)
Publishing date:

Info

Title:
Research progress in application of strontium aluminate long afterglow luminescent materials in road markings
Author(s):
HE Rui1 LIANG Ying-ping1 XIE Rui-song2 LU Xiao-song1 GENG Jiu-guang1
(1. School of Materials Science and Engineering, Chang'an University, Xi'an 710061, Shaanxi, China; 2. Shaanxi Communications Holding Group Co,. Ltd, Xi'an 710065, Shaanxi, China)
Keywords:
road engineering road marking strontium aluminate long afterglow luminescent material luminescence mechanism performance evaluation surface modification
PACS:
U491.523
DOI:
10.19721/j.cnki.1671-8879.2022.03.001
Abstract:
In order to promote the application and research of long afterglow luminescent materials in road markings, and improve the visibility of road markings in rainy night, the existing research and application results at home and abroad were combed. And the classification and luminescence mechanism of long afterglow luminescent materials were described. In addition, the preparation methods of long afterglow luminescent materials were summarized. Then, the key performance evaluation methods of strontium aluminate(SrAl2O4:Eu2+, Dy3+)luminescent materials doped with rare earth elements Europium and Dy3+ in road markings were discussed, laying a foundation for further improving its technical standards. In view of the problems of easy hydrolysis and poor organic compatibility of sral2o3: Eu2+, Dy3+ luminescent materials, the effects of surface modification technology and formula optimization on improving their water resistance and organic compatibility were discussed. The results show that it is found that the long afterglow luminescent materials in road markings mainly include sulfide, aluminate and silicate series. Among them, SrAl2O4: Eu2+, Dy3+ has the advantages of long afterglow time and high afterglow intensity, and is the most widely used in road markings. When the mass content of this type of long afterglow luminescent material is 30 to 40% and the particle size in range of 25 to 48 μm the use effect in road marking is the best. It is an effective means of water resistance and organic compatibility, in which the composite modification technology can simultaneously improve the water resistance and organic compatibility of the strontium aluminate luminescent material.6 tabs, 5 figs, 51 refs.

References:

[1] 张云龙.交通控制设施的可视性与交通安全[J].中国公路,2019(15):59-60.
ZHANG Yun-long.Visibility of traffic control facilities and traffic safety[J].China Highway,2019(15):59-60.
[2]BURNS D M,HEDBLOM T P,MILLER T W.Modern pavement marking systems:Relationship between optics and nighttime visibility[J].Transportation Research Record,2008(2056):43-51.
[3]ZHANG G H,HUMMER J E,RASDO88RF W.Impact of bead density on paint pavement marking retroreflectivity[J].Journal of Transportation Engineering,2010,136(8):773-781.
[4]汪 桥,朱建华,台德进.一种具有交通信号灯功能的交通标线及可变更的车道指示线:中国,CN201710394666.3[P].2017-05-29.
WANG Qiao,ZHU Jian-hua,TAI Jin-de.The utility model relates to a traffic marking with the function of a traffic signal lamp and a changeable Lane indication line:China,CN201710394666.3[P].2017-05-29.
[5]朱本成,郭忠印,宋灿灿.透光混凝土基LED主动发光交通标线的光纤设置[J].同济大学学报(自然科学版),2019,47(6):802-809.
ZHU Ben-cheng,GUO Zhong-yin,SONG Can-can.Fiber-optic parameters of light emitting diode active-luminous traffic markings based on light-transmitting concrete[J].Journal of Tongji University(Natural Science),2019,47(6):802-809.
[6]RICHES B,DEXTER T,ARISTA J P,et al.Evaluation of strontium aluminate in traffic paint pavement markings for rural and unilluminated roads[J].Journal of the Eastern Asia Society for Transportation Studies,2015,11:1726-1744.
[7]周永强,刘海涛,田一光,等.稀土硅酸盐长余辉发光材料的制备及性能[J].稀有金属材料与工程,2010,39(增2):512-515.
ZHOU Yong-qiang,LIU Hai-tao,TIAN Yi-guang,et al.Preparation and properties of rare earth silicate long afterglow luminescent materials[J].Rare Metal Materials and Engineering,2010,39(S2):512-515.
[8]张 丽,胡建伟,冯蒙丽,等.掺杂长余辉发光材料的研究概况[J/OL].化工新型材料:1-10[2022-01-19].http://kns.cnki.net/kcms/detail/11.2357.TQ.20210303.1313.008.html.
ZHANG Li,HU Jian-wei,FENG Meng-li,et al.Research status of doped long afterglow luminescent materials[J].New Chemical Materials,1-10[2022-01-19].http://kns.cnki.net/kcms/detail/11.2357.TQ.20210303.1313.008.html.
[9]储志强,刘东华,周康宁,等.碱土铝酸盐长余辉发光材料的研究进展与发展方向[J].金属材料与冶金工程,2019,47(1):27-32.
CHU Zhi-qiang,LIU Dong-hua,ZHOU Kang-ning,et al.Research progress and development trend of alkaline earth aluminates long-lasting phosphorescent material[J].Metal Materials and Metallurgy Engineering,2019,47(1):27-32.
[10]MATSUZAWA T,AOKI Y,TAKEUCHI N,et al.A new long phosphorescent phosphor with high brightness,SrAl2O4:Eu2+,Dy3+[J].Journal of the Electrochemical Society,1996,143(8):2670-2673.
[11]VITOLA V,MILLERS D,BITE I,et al.Recent progress in understanding the persistent luminescence in SrAl2O4:Eu,Dy[J].Materials Science and Technology,2019,35(14):1661-1677.
[12]姚伯龙,杨同华,罗 侃,等.蓄能发光功能涂料研究及其应用[J].涂料工业,2007,37(12):38-41.
YAO Bo-long,YANG Tong-hua,LUO Kan,et al.Study of the functional energy storage luminescent paint and its application[J].Paint & Coatings Industry,2007,37(12):38-41.
[13]AITASALO T,HOLSA J,JUNGNER H,et al.Thermoluminescence study of persistent luminescence materials:Eu2+- and R3+-doped calcium aluminates,CaAl2O4:Eu2+,R3+[J].The Journal of Physical Chemistry B,2006,110(10):4589-4598.
[14]CLABAU F,ROCQUEFELTE X,JOBIC S,et al.Mechanism of phosphorescence appropriate for the long-lasting phosphors Eu2+-doped SrAl2O4 with codopants Dy3+ and B3+[J].Chemistry of Materials,2005,17(15):3904-3912.
[15]陈 林.发光透水混凝土路面工程技术研究[D].重庆:西南大学,2020.
CHEN Lin.Research on engineering technology of luminous permeable concrete pavement[D].Chongqing:Southwest University,2020.
[16]李松坤,王小平,王丽军,等.长余辉发光材料的研究进展[J].材料导报,2014,28(5):63-67,84.
LI Song-kun,WANG Xiao-ping,WANG Li-jun,et al.Research progress on long persistence luminescent materials[J].Materials Review,2014,28(5):63-67,84.
[17]何 倍,高英力,冷 政,等.光致发光水泥基复合材料的强度与光学特性研究[J].功能材料,2019,50(7):7126-7133,7138.
HE Bei,GAO Ying-li,LENG Zheng,et al.Study on strength and optical properties of photoluminescence cement-based composites materials[J].Journal of Functional Materials,2019,50(7):7126-7133,7138.
[18]ANESH M P,GULREZ S K H,ANIS A,et al.Developments in Eu2+-doped strontium aluminate and polymer/strontium aluminate composite[J].Advances in Polymer Technology,2014,33(S1):1-9.
[19]HAN S D,SINGH K C,CHO T Y,et al.Preparation and characterization of long persistence strontium aluminate phosphor[J].Journal of Luminescence,2008,128(3):301-305.
[20]DU H L,SHAN W F,WANG L Y,et al.Optimization and complexing agent-assisted synthesis of green SrAl2O4:Eu2+,Dy3+ phosphors through Sol-gel process[J].Journal of Luminescence,2016,176:272-277.
[21]武利民.铝酸锶长余辉材料的可控合成及性能[D].长沙:湖南大学,2014.
WU Li-min.Controlled synthesis and properties of the strontium aluminates long afterglow phosphors[D].Changsha:Hunan University,2014.
[22]吴 谨.基于视觉特性的荧光标线涂料研发及模拟分析[D].重庆:重庆交通大学,2019.
WU Jin.Development and simulation analysis of fluorescent marking coatings based on visual characteristics[D].Chongqing:Chongqing Jiaotong University,2019.
[23]LYU L,CHEN Y X,YU L T,et al.The improvement of moisture resistance and organic compatibility of SrAl2O4:Eu2+,Dy3+ persistent phosphors coated with silica-polymer hybrid shell[J].Materials(Basel,Switzerland),2020,13(2):426.
[24]李峻峰,邱克辉,赖雪飞,等.PMMA包覆铝酸锶发光粉的制备与表征[J].化工新型材料,2010,38(8):44-45,91.
LI Jun-feng,QIU Ke-hui,LAI Xue-fei,et al.Preparation and characterization of PMMA-coated strontium aluminate phosphor[J].New Chemical Materials,2010,38(8):44-45,91.
[25]邢文男.硅丙乳液铝酸锶发光涂料的制备[D].沈阳:沈阳理工大学,2015.
XING Wen-nan.Preparation of silicone-acrylic emulsion strontium aluminates luminous coating[D].Shen-yang:Shenyang Ligong University,2015.
[26]张 宇.水基长余辉复合涂层的制备与性能优化[D].吉林:东北电力大学,2020.
ZHANG Yu.Preparation and performance optimization of water-based long afterglow composite coating[D].Jilin:Northeast Dianli University,2020.
[27]吴卓科,李菁若,潘 岳,等.基于长余辉发光材料的荧光涂层的制备工艺研究[J].公路交通技术,2019,35(5):25-29,35.
WU Zhuo-ke,LI Jing-ruo,PAN Yue,et al.Study on preparation technology of fluorescent coating based on long-lasting phosphor materials[J].Technology of Highway and Transport,2019,35(5):25-29,35.
[28]JT/T 280—2004,路面标线涂料[S].
JT/T 280—2004,Pavement marking paint[S].
[29]JT/T 712—2008,路面防滑涂料[S].
JT/T 712—2008,Pavement antiskid paint[S].
[30]JC/T 1015—2006,环氧树脂地面涂层材料[S].
JC/T 1015—2006,Epoxy resin flooring coating[S].
[31]HARANATH D,SHANKER V,CHANDER H,et al.Studies on the decay characteristics of strontium aluminate phosphor on thermal treatment[J].Materials Chemistry and Physics,2003,78(1):6-10.
[32]刘晓林,邹新阳,施 磊,等.铝酸盐长余辉发光涂料光学性能研究[J].稀有金属,2008,32(4):502-505.
LIU Xiao-lin,ZOU Xin-yang,SHI Lei,et al.Optical characteristics of aluminates luminescent coatings with long-lasting luminescence[J].Chinese Journal of Rare Metals,2008,32(4):502-505.
[33]高珊珊.新型发光涂料耐磨性的研究[D].贵阳:贵州大学,2006.
GAO Shan-shan.Study on wear resistance of new luminescent coatings[D].Guiyang:Guizhou University,2006.
[34]徐安花.掺废旧陶瓷颗粒的道路标线涂料技术性能[J].武汉理工大学学报,2014,36(6):54-57.
XU An-hua.Performance of road marking materials incorporated waste ceramic particles[J].Journal of Wuhan University of Technology,2014,36(6):54-57.
[35]李 刚.公路自发光标线配合比设计[J].辽宁省交通高等专科学校学报,2018,20(1):5-8.
LI Gang.Mixture ratio design of the spontaneous cursor line[J].Journal of Liaoning Provincial College of Communications,2018,20(1):5-8.
[36]黄韦星,曾和平,余 力,等.储能自发光涂料的研制及性能[J].华南师范大学学报(自然科学版),2011,43(3):66-70.
HUANG Wei-xing,ZENG He-ping,YU Li,et al.Preparation and properties of energy storage self-luminous coatings[J].Journal of South China Normal University(Natural Science Edition),2011,43(3):66-70.
[37]董元帅,侯 芸,薛忠军.基于道路安全的蓄能发光材料配伍性研究[J].公路,2020,65(5):272-280.
DONG Yuan-shuai,HOU Yun,XUE Zhong-jun.Research on compatibility of energy storage luminescent materials based on road safety[J].Highway,2020,65(5):272-280.
[38]曹雪娟,单柏林,丁勇杰,等.高发光长余辉发光涂料的制备及性能[J].电镀与涂饰,2021,40(8):648-653.
CAO Xue-juan,SHAN Bai-lin,DING Yong-jie,et al.Preparation and properties of high-brightness long-afterglow luminescent paint[J].Electroplating & Finishing,2021,40(8):648-653.
[39]刘成楼.水性长余辉蓄能发光涂料的研制[J].现代涂料与涂装,2008,11(7):39-41,44.
LIU Cheng-lou.Development of the long afterglow energy storage waterborne luminescent paint[J].Modern Paint & Finishing,2008,11(7):39-41,44.
[40]王 德,黄 玮,丛玉凤,等.长余辉蓄能发光涂料的研制[J].涂料工业,2013,43(3):29-31,45.
WANG De,HUANG Wei,CONG Yu-feng,et al.Development of long-afterglow energy storage luminescence paint[J].Paint & Coatings Industry,2013,43(3):29-31,45.
[41]李智佳.环氧树脂长余辉蓄能发光涂料的研究[D].大连:大连工业大学,2017.
LI Zhi-jia.Study on long afterglow energy storage luminescent paint of epoxy resin[D].Dalian:Dalian Polytechnic University,2017.
[42]杨 波,邓 华.基于驾驶员眼动特征的蓄能荧光标线诱导特性及设置方法[J].科学技术与工程,2020,20(35):14694-14700.
YANG Bo,DENG Hua.Inducing characteristics and setting method of energy storage fluorescent marking based on driver's eye movement characteristics[J].Science Technology and Engineering,2020,20(35):14694-14700.
[43]邵 岩,刘 勇,曹 源,等.自发光交通标志在农村公路中的应用研究[J].现代交通技术,2019,16(5):35-41.
SHAO Yan,LIU Yong,CAO Yuan,et al.Study on application of self-luminous traffic signs on rural highway[J].Modern Transportation Technology,2019,16(5):35-41.
[44]李瑞芳.SrAl2O4:Eu2+,Dy3+发光粉的表面改性及应用研究[D].大连:大连理工大学,2009.
LI Rui-fang.Studies on the surface modification and application of SrAl2O4:Eu2+,Dy3+ phosphor[D].Dalian:Dalian University of Technology,2009.
[45]张 柳,裴建中,李 蕊.表面修饰对道路标线发光材料耐水性的影响[J].中国资源综合利用,2018,36(2):25-27.
ZHANG Liu,PEI Jian-zhong,LI Rui.Effect of surface modification on water resistance of luminescent powder[J].China Resources Comprehensive Utilization,2018,36(2):25-27.
[46]张永威,朱亚楠,葛明桥.SrAl2O4:Eu2+,Dy3+长余辉发光粉末表面改性及表征[J].化工新型材料,2020,48(12):93-96.
ZHANG Yong-wei,ZHU Ya-nan,GE Ming-qiao.Surface modification and characterization of SrAl2O4:Eu2+, Dy3+ long afterglow luminescence powder[J].New Chemical Materials,2020,48(12):93-96.
[47]余宏军.铝酸锶发光粉的包覆改性[D].广州:华南理工大学,2012.
YU Hong-jun.Coating modification of strontium aluminate phosphor[D].Guangzhou:South China University of Technology,2012.
[48]NANCE J,SPARKS T D.From streetlights to phosphors:A review on the visibility of roadway markings[J].Progress in Organic Coatings,2020,148:105749.
[49]NANCE J,SPARKS T D.Comparison of coatings for SrAl2O4:Eu2+,Dy3+ powder in waterborne road striping paint under wet conditions[J].Progress in Organic Coatings,2020,144:105637.
[50]BI Y Q,PEI J Z,CHEN Z X,et al.Preparation and characterization of luminescent road-marking paint[J].International Journal of Pavement Research and Technology,2021,14(2):252-258.
[51]孙顺杰.长余辉发光材料在涂料中的应用[J].涂料技术与文摘,2012,33(9):3-7.
SUN Shun-jie.Application of long-afterglow luminescent materials in coatings[J].Coatings Technology & Abstracts,2012,33(9):3-7.

Memo

Memo:
-
Last Update: 2022-07-01