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Fabrication of nanoporous silica aerogels with low density(PDF)

长安大学学报(自然科学版)[ISSN:1006-6977/CN:61-1281/TN]

Issue:
2010年04期
Page:
107-110
Research Field:
Publishing date:
2010-08-20

Info

Title:
Fabrication of nanoporous silica aerogels with low density
Author(s):
GENG Gang-qiang1 WANG Shan-yue2 BI Wei-tao1 MA Rui-jie1 BIAN Gong-xun1
1. School of Material Science and Engineering, Chang'an University, Xi'an 710061, Shaanxi, China; 2. Jiangsu Qiming Environment Protection and Energy Saving Technology Co Ltd, Suzhou 215004, Jiangsu, China
Keywords:
material engineering sodium silicate nanoporous aerogel silica ion exchange
PACS:
O648
DOI:
-
Abstract:
The SiO2 aerogels of low density was fabricated by ion exchange and sol-gel method on the basis of sodium silicate. The effect of pH value, annealed temperature and solvent exchange process on the gel time, aerogel density, porosity and the micro-structure was studied. The results show that when the pH value is 6, the gel system is annealed at 50 ℃ for 84 h, 60 ℃ for 72 h, and a mixed trimethyl chlorosilane, n-hexane and isopropyl alcohol solution is used for surface modification, the best quality of silica aerogels with low density(0.2 g/cm3), higher porosity(90.1%)and pore size of 20~40 nm can be obtained. 4 tabs, 5 figs, 8 refs.

References:

[1] Lawrence W H.Aerogel applications[J].Journal of Non-Crystalline Solids,1998,225:335-342.
[2]Wang J,Shen J,Zhou B,et al.Cluster structure of silica aerogel investigated by laser ablation[J].Nano-Structured Materials,1998,10(6):909-916.
[3]Stolarski M,Walendziewski J,Steininger M,et a1.Synthesis and characteristic of silica aerogels[J].Applied Catalysis A:General,1999,177(2):139-148.
[4]Hegde N D,Rao A V.Effect of processing temperature on relation and physical properties of low density TEOS based silica aerogels[J].Journal of Sol-Gel Science and Technology,2006,38(1):55-61.
[5]Kistler S S.Coherent expanded aerogels and jellies[J].Nature,1931,227:741.
[6]Mari-ann E,Elin N.Thermal and temporal aging of silica gels in monomer solutions[J].Journal of Sol-Gel Science and Technology,1994,13(1/3): 317-322.
[7]Schaefer D W.Polymers,fractals,and ceramic materials[J].Science,1989,243:1023-1027.
[8]Schmidt M,Schwertfeger F.Applications for silica aerogel products[J].Journal of Non-Crystalline Solids,1998,225:364-368.

Memo

Memo:
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Last Update: 2010-08-20