[1]王小庆,司 伟,马 骉,等.新型环氧树脂复合相变材料对沥青混合料调温性能影响[J].长安大学学报(自然科学版),2024,44(2):34-45.[doi:10.19721/j.cnki.1671-8879.2024.02.004]
 WANG Xiao-qing,SI Wei,MA Biao,et al.Influence of epoxy resin composite phase change material on road and temperature regulation performance of asphalt mixture[J].Journal of Chang’an University (Natural Science Edition),2024,44(2):34-45.[doi:10.19721/j.cnki.1671-8879.2024.02.004]
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新型环氧树脂复合相变材料对沥青混合料调温性能影响()
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长安大学学报(自然科学版)[ISSN:1006-6977/CN:61-1281/TN]

卷:
第44卷
期数:
2024年2期
页码:
34-45
栏目:
道路工程
出版日期:
2024-03-01

文章信息/Info

Title:
Influence of epoxy resin composite phase change material on road and temperature regulation performance of asphalt mixture
文章编号:
1671-8879(2024)02-0034-12
作者:
王小庆1司 伟12马 骉1王 薇3于 淼4
(1. 长安大学 公路学院,陕西 西安 710064; 2. 西藏天路股份有限公司 博士后科研工作站,西藏 拉萨 850000; 3. 四川久马高速公路有限责任公司,四川 阿坝藏族羌族自治州 610000; 4. 西安公路研究院有限公司,陕西 西安 710064)
Author(s):
WANG Xiao-qing1 SI Wei12 MA Biao1 WANG Wei3 YU Miao4
(1. School of Highway, Chang'an University, Xi'an 710064, Shaanxi, China; 2. Postdoctoral Research Station,Xizang Tianlu Co. Ltd., Lhasa 850000, Xizang, China; 3. Sichuan Jiuma Expressway Co. Ltd.,Aba Xizang and Qiang Autonomous Prefecture 610000, Sichuan, China; 4. Xi'an Highway Research Institution, Xi'an 710064, Shaanxi, China)
关键词:
道路工程 沥青混合料 试验研究 相变材料 路用性能 温度调控
Keywords:
road engineering asphalt mixture experimental research phase change materials road performance temperature regulation
分类号:
U416.2
DOI:
10.19721/j.cnki.1671-8879.2024.02.004
文献标志码:
A
摘要:
为解决相变材料用于沥青混合料热稳定性与力学性能不足的问题,采用环氧树脂与十五烷定形封装相变材料制备新型环氧树脂复合相变材料,并采用等体积替换法将其用于沥青混合料中。采用差示扫描量热仪(DSC)、热重分析仪(TG)与导热系数仪进行环氧树脂复合相变材料相变与热物特性测试分析; 通过相变沥青混合料温度调控试验分析其调温性能与效果,并对相变沥青混合料路用性能进行验证。研究结果表明:环氧树脂复合相变材料相变焓值可达60 J/g以上,在180 ℃以内几乎不发生热损失,储热密度高、热稳定性良好; 相变区间内表观比热容显著增大,升、降温过程中最大值分别为10.9和6.7J/(g?℃); 相变材料掺量(质量分数)越大温度调控效果越好; 调温性能与混合料位置相关,相变沥青混合料最大调温温差和最大温度变化速率降低值随深度增大而增大; 各掺量下相变沥青混合料均具有显著的调温效果,掺量小于4%时相变沥青混合料均可满足路用性能要求。
Abstract:
To solve the problem of insufficient thermal stability and mechanical properties of phasechange materials for asphalt mixture, a new type of epoxy resin composite phase change materialwas prepared by using epoxy resin composite and pentadecane shaped encapsulation phase changematerial, and equal volume substitution method was used in asphalt mixture. The phase change andthermal properties of epoxy resin composite phase change materials were tested and analyzed by differential scanning calorimetry(DSC), differential thermal(TG)analysis and thermalconductivity meter. The temperature regulation performance and effect of phase change asphaltmixture were analyzed by temperature regulation test, and the road performance of phase changeasphalt mixture was verified. The results show that the phase change enthalpy of epoxy resincomposite phase change material can reach more than 60 J/g, and there is almost no heat losswithin 180 °C, with high heat storage density and good thermal stability. The apparent specificheat capacity increases significantly in the phase change interval, and the maximum values are10.9 and 6.7 J/(g?℃)during the heating and cooling process, respectively. The greater the content of phase change material, thebetter the temperature regulation effect, the temperature regulation performance is also related tothe location of the mixture. The maximum temperature difference and the maximum temperaturechange rate of the phase change asphalt mixture increase with the increase of depth. The phasechange asphalt mixture has significant temperature regulation effect under each content. When thecontent of epoxy resin composite phase change material is less than 4%, the phase change asphaltmixture can meet the road performance requirements.7 tabs, 13 figs, 25 refs.

参考文献/References:

[1] CHENG H L,LIU J N,SUN L J,et al.Fatigue behaviours of asphalt mixture at different temperatures in four-point bending and indirect tensile fatigue tests[J].Construction and Building Materials,2021,273:121675.
[2]ABDULLAH M E,AHMAD Z K,HAININ M R,et al.High temperature characteristics of warm mix asphalt mixtures with nanoclay and chemical warm mix asphalt modified binders[J].Journal of Cleaner Production,2016,122:326-334.
[3]申爱琴,靳欣宽,郭寅川,等.耦合场下陕北地区半刚性沥青路面力学响应分析[J].长安大学学报(自然科学版),2022,42(5):1-11.
SHEN Ai-qing,JIN Xin-kuan,GUO Yin-chuan,et al.Mechanical response analysis of semi-rigid asphalt pavement in Northern Shaanxi under coupling field[J].Journal of Chang'an University(Natural Science Edition),2022,42(5):1-11.
[4]LI N,WANG J E,SI W,et al.Quantitative analysis of adhesion characteristics between crumb rubbermodified asphalt and aggregate using surface free energy theory[J].Materials,2022,15(16):5735.
[5]蔡俊华.玻璃纤维超薄罩面沥青混合料路用性能[J].长安大学学报(自然科学版),2019,39(5):20-27.
CAI Jun-hua.Road performance of glass fiber ultra-thin overlay asphalt mixture[J].Journal of Chang'an University(Natural Science Edition),2019,39(5):20-27.
[6]FERREIRA J L S,BABADOPULOS L F A L,BASTOS J B S,et al.A tool to design rutting resistantasphalt mixes through aggregate gradation selection[J].Construction and BuildingMaterials,2020,236:117531.
[7]GUDIPUDI P P,UNDERWOOD B S,ZALGHOUT A.Impact of climate change on pavementstructural performance in the United States[J].Transportation Research Part D,2017,57:172-184.
[8]MA B,ADHIKARI S,CHANG Y J,et al.Preparation of composite shape-stabilized phase changematerials for highway pavements[J].Construction and Building Materials,2013,42:114-121.
[9]MANNING B J,BENDER P R,COTE S A,et al.Assessing the feasibility of incorporating phasechange material in hot mix asphalt[J].Sustainable Cities and Society,2015,19:11-16.
[10]ANUPAM B R,SAHOO U C,RATH P.Phase change materials for pavement applications:A review[J].Construction and Building Materials,2020,247:118553.
[11]WEI K,WANG Y C,MA B.Effects of microencapsulated phase change materials on theperformance of asphalt binders[J].Renewable Energy,2019,132:931-940.
[12]PHAN T M,PARK D W,HO M L T.Improvement on rheological property of asphalt binderusing synthesized micro-encapsulation phase change material[J].Construction and BuildingMaterials,2021,287:123021.
[13]CHEN Y,WANG H N,YOU Z P,et al.Application of phase change material in asphalt mixture-Areview[J].Construction and Building Materials,2020,263:120219.
[14]赵梦阳,张宇昂,唐炳涛.聚氨酯型复合定形相变储能材料研究进展[J].精细化工,2020,37(11):2182-2192,2215.
ZHAO Meng-yang,ZHANG Yu-ang,TANG Bing-tao.Research process in polyurethane form-stable composite phasechange materials[J].Fine Chemicals,2020,37(11):2182-2192,2215.
[15]WEI K,LIU Z,WANG L,et al.Preparation of polyurethane solid-solid low temperature PCMsgranular asphalt mixes and study of phase change temperature control behavior[J].SolarEnergy,2022,231:149-157.
[16]JIN F L,LI X,PARK S J.Synthesis and application of epoxy resins:A review[J].Journal ofIndustrial and Engineering Chemistry,2015,29:1-11.
[17]丁 泽,陈昭朋,张 凯,等.相变微胶囊/环氧树脂复合泡沫的制备及性能[J].高分子材料科学与工程,2019,35(1):136-141.
DING Ze,CHEN Zhao-ming,ZHANG Kai,et al. Preparation and properties of phase change microcapsule/epoxyresin composite foam[J].Polymer Materials Science & Engineering,2019,35(1):136-141.
[18]WANG Z Y,SITU W F,LI X X,et al. Novel shape stabilized phase change material based onepoxy matrix with ultrahigh cycle life for thermal energy storage[J]. Applied ThermalEngineering,2017,123:1006-1012.
[19]CHENG P,WEI K,SHI W S,et al. Preparation and performance analysis of phase changemicrocapsule/epoxy resin composite phase change material[J]. Journal of Energy Storage,2022,47:103581.
[20]马 骉,肖 悦,张文静,等.环氧树脂复合相变材料基本性能研究[J]. 硅酸盐通报,2018,37(8):2536-2542.
MA Biao,XIAO Yue,ZHANG Wen-jing,et al.Basic properties of epoxy resin composite phase change material[J].Bulletin of the Chinese Ceramic Society,2018,37(8):2536-2542.
[21]WANG X Q,MA B,WEI K,et al.Thermal stability and mechanical properties of epoxy resin/microcapsule composite phase change materials[J]. Construction and Building Materials,2021,312:125392.
[22]VÉLEZ C,ORTIZ D Z J M,KHAYET M.Thermal properties of n-pentadecane,n-heptadecane and n-nonadecane in the solid/liquid phase change region[J].International Journal of Thermal Sciences,2015,94:139-146.
[23]李伟培,何世杰,邱志明,等.载体孔属性对多孔复合PCMs热性能的影响:综述[J].材料导报,2021,35(增1):495-500.
LI Wei-pei,HE Shi-jie,QIU Zhi-ming,et al. Influence of structure and properties of porous carrier on thermal properties of multi-scale porous PCMs composite:A review[J]. Materials Reports,2021,35(S1):495-500.
[24]黄 维.环氧树脂复合相变调温剂小试制备及其性质研究[D].西安:长安大学,2017.
HUANG Wei.Small scale preparation and property research of epoxy resin composite phase change thermoregulation agent[D].Xi'an:Chang'an University,2017.
[25]冉武平,凌建明,谷志峰.环氧沥青混合料低温性能及评价指标[J].西南交通大学学报,2017,52(5):935-942.
RAN Wu-ping,LING Jian-ming,GU Zhi-feng.Low temperature performance and evaluation index of epoxy asphalt mixture[J].Journal of Southwest Jiaotong University,2017,52(5):935-942.

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备注/Memo

备注/Memo:
收稿日期:2023-09-18
基金项目:国家自然科学基金项目(52278430); 西藏自治区天路科研创新发展基金项目(XZ 2019 TL-G-04); 中国博士后科学基金项目(2022MD713805)
作者简介:王小庆(1993-),男,陕西榆林人,工学博士研究生,E-mail:wangxiaoqing716@163.com。
通讯作者:司 伟(1986-),男,甘肃会宁人,副教授,博士研究生导师,E-mail:siwei@chd.edu.com。
更新日期/Last Update: 2024-03-01